Molecules and Compounds
Terms
- Electronegativity
- Can be used to to determine type of bond based on electronegativity difference.
- Ionic Bond
- Covalent Bond
- Polar Covalent Bond
- Sharing of electrons.
- Hydrogen Bond
- Hydrogen is bonded with an electronegative element.
Prefixes
Prefix | Value |
---|---|
mono- | |
di- | |
tri- | |
tetra- | |
penta- |
Prefix | Value |
---|---|
hexa- | |
hepta- | |
octa- | |
nona- | |
deca- |
Formula Summary
Formal Charge (Option 1)
Given some element which has number of valance electrons, and a lewis diagram of bonded () electrons and non-bonded () electrons, the formal charge for the given element in the lewis structure is
For the given quantities
Formal Charge (Option 2)
Given some element which has number of valance electrons, and a lewis diagram of some number of bonds () and dots (), the formal charge for the given element in the lewis structure is
For the given quantities
Note: each bond is 2 electrons, but counts as one bond.
Polyatomic Ions
Remembering the number of oxygens
General
Given a set of oxygens in increasing order
Where
For example
Given some element or compound ionically bonded with such
For example
The following table denotes the naming conventions therein
Prefix | Prefix Meaning (relative to suffix) | Suffix | Oxygen Order | Example | |
---|---|---|---|---|---|
Formula | Name | ||||
Per- | More than | -ate | Highest # | Perchlorate | |
-ate | Higher # | Chlorate | |||
-ite | Lower # | Chlorite | |||
Hypo- | less than | -ite | Lowest # | Hypochlorite |
Oxygen vs No-Oxygen Comparison
Prefix | Suffix | Meaning | Example | Name |
---|---|---|---|---|
Per- | -ate | or | Persulfate | |
-ate | Sulfate | |||
-ite | Sulfite | |||
Hypo- | -ite | Hyposulfite | ||
-ide | No oxygennon-metal | Sulfide |
In summary
Per*ate
Greater than
- *ate
- *ite
- Hypo*ite
*ate
Less than
- Per*ate
Greater than
- *ite
- Hypo*ite
*ite
Less than
- Per*ate
- *ate
Greater than
- Hypo*ite
Hypo*ite
Less than
- Per*ate
- *ate
- *ite
Generally
per-ate | Used in the ion with the largest number of oxygen atoms |
---|---|
-ate-ite | Polyatomic ions of oxygen |
hypo-ite | Used in the ion with the lowest number of oxygen atoms |
-ide | Non-metal, no oxygens |
Determining The Charge†
Warning
Phosphate () is the only one that violates this rule!
Ionic Lewis Structures
Ionic Lewis Structures
Examples
Notes
- When naming an ionic compound, the name of the cation is followed by the name of the anion. Monatomic anions are named with the ending -ide.