Molecules and Compounds

Terms

Electronegativity
Can be used to to determine type of bond based on electronegativity difference.
Ionic Bond
Covalent Bond
Polar Covalent Bond
Sharing of electrons.
Hydrogen Bond
Hydrogen is bonded with an electronegative element.

Prefixes

PrefixValue
mono-
di-
tri-
tetra-
penta-
PrefixValue
hexa-
hepta-
octa-
nona-
deca-

Formula Summary

Formal Charge (Option 1)

Given some element which has number of valance electrons, and a lewis diagram of bonded () electrons and non-bonded () electrons, the formal charge for the given element in the lewis structure is

For the given quantities

Formal Charge (Option 2)

Given some element which has number of valance electrons, and a lewis diagram of some number of bonds () and dots (), the formal charge for the given element in the lewis structure is

For the given quantities

Note: each bond is 2 electrons, but counts as one bond.

Polyatomic Ions

Remembering the number of oxygens

General

Given a set of oxygens in increasing order

Where

For example

Given some element or compound ionically bonded with such

For example

The following table denotes the naming conventions therein

PrefixPrefix Meaning

(relative to suffix)
SuffixOxygen OrderExample
FormulaName
Per-More than-ateHighest #Perchlorate
-ateHigher #Chlorate
-iteLower #Chlorite
Hypo-less than-iteLowest #Hypochlorite
Oxygen vs No-Oxygen Comparison
PrefixSuffixMeaningExampleName
Per--ate or Persulfate
-ateSulfate
-iteSulfite
Hypo--iteHyposulfite
-ideNo oxygennon-metalSulfide

In summary

Per*ate


Greater than

  • *ate
  • *ite
  • Hypo*ite

*ate


Less than

  • Per*ate

Greater than

  • *ite
  • Hypo*ite

*ite


Less than

  • Per*ate
  • *ate

Greater than

  • Hypo*ite

Hypo*ite


Less than

  • Per*ate
  • *ate
  • *ite

Generally

per-ateUsed in the ion with the largest number of oxygen atoms
-ate-itePolyatomic ions of oxygen
hypo-iteUsed in the ion with the lowest number of oxygen atoms
-ideNon-metal, no oxygens

Determining The Charge

Warning

Phosphate () is the only one that violates this rule!

Example for Nitrate

Example for Cyanide

Example for Oxalate

Example for Hydrogen Carbonate

Source

Ionic Lewis Structures

Ionic Lewis Structures

Examples
Lewis structure for sulfate ion

Notes